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3D Printing: Emissions Research and Your Health

The increasing popularity of 3D printing has revolutionized products and designs from industrial prototyping to educational, commercial, and residential environments. This technology’s prominence in non-industrial spaces like classrooms, makerspaces, and residence halls makes understanding the health and safety risks paramount.

While 3D printing offers innovation and potential, the process introduces a critical public health concern – the potential release of airborne contaminants during operation. To address the public health risks associated with 3D printing, our research helps identify chemical emissions and deliver science-based solutions to enhance 3D printing safety across user groups.

Male engineering student looking at 3D printer

What is 3D printing?

3D printing is a form of additive manufacturing that builds three-dimensional objects layer by layer from a digital file. This technology is used across many sectors, including:

  • Medical and dental devices
  • Aerospace and defense components
  • Automotive parts
  • Educational tools
3D printer creating an object

3D Printing Safety Concerns: Emissions and Health Risks

Chemical Insights’ research focuses on the two most common consumer-grade technologies: Material extrusion (filament-based) and Vat polymerization (resin-based). Despite their widespread use, both techniques introduce contaminants that can pose human health hazards throughout printing.

Abstract background of blue particles flowing mid air

Volatile organic compounds (VOCs)

During operation, 3D printers release a complex mixture of volatile organic compounds that often exceeds 200 distinct species. VOCs easily evaporate into the air and can be inhaled.

Health impact

Many detected VOCs are known irritants, odorants, and carcinogens. Short-term exposure can cause eye, nose, and throat irritation in addition to headaches and nausea. Long-term exposure is associated with damage to the liver and central nervous system, cardiovascular disease, cancer, and asthma.

Resin hazard

In the vat polymerization of 3D printing technique, a vat filled with a resin is cured — or hardened — into a solid by exposure to UV light. The uncured resin itself is a source of VOCs that can be emitted even when the printer is simply loaded and turned off.

Fine and ultrafine particles (UFPs)

UFPs are generally smaller than 100 nanometers. Due to their minuscule size, they can be inhaled deep into the lungs, absorbed into the bloodstream, and potentially even reach the brain. Research found that particle emissions could reach up to one trillion particles per hour.  In poorly ventilated spaces, particle mass concentrations (PM2.5) near an operating printer can exceed outdoor levels found near a busy highway.

Other hazards

In addition to airborne emissions, the 3D printing process presents several physical safety risks:

  • Dermal Exposure: Resins and solvents contain sensitizers that can cause allergic reactions and skin irritation.
  • Burns: Contact with hot surfaces, such as the heated nozzle and build plate, poses a risk of burns
  • Mechanical and Electrical: Hazards exist from unguarded moving parts and internal electrical components.

3D Printing Research in Real-World Environments

The resin challenge in dental schools

Dental resin 3D printing is a key technology in modern dentistry for crowns, bridges, and dentures. Chemical Insights researched exposure to chemical hazards within dental schools during the resin 3D printing and post-printing processes.

High VOC release

Research in a university dental school found that the resin 3D printing room had the highest total VOC (TVOC) levels and the greatest number of VOCs detected compared to the grinding area and outdoors. This indicates that the printing process emitted a complex mixture of VOCs. Although the printing and post-printing processes increased specific VOC levels in the educational setting, overall concentrations of hazardous chemicals didn’t exceed recommended indoor reference levels.

Chemical exposure

Specific hazardous chemicals identified include:

  • Isopropanol: Detected consistently at high concentrations attributed to its use as the wash solvent during the post-printing process.
  • Carcinogens: Chemicals of concern detected in the printing area included acetaldehyde and formaldehyde. Other detected possible carcinogens included (1-methylethyl) benzene and 1-4-dichlorobenzene.
  • Other hazards: The detected chemicals include a total of 29 chemicals of concern classified as irritants, sensitizers, asthmagens, and developmental toxicants in the printing area.
dental prosthesis made with dental resins
Chemical Insights’ research targets specific environments where 3D printing is routinely used to understand the true impact on indoor air quality.

The filament factor in classroom settings

Material extrusion printers commonly found in schools and makerspaces pose exposure risks to vulnerable populations, such as children, older adults, people with pre-existing respiratory conditions, and more.  Our research on 3D printing in the classroom highlights how emissions can affect students and educators, primarily due to UFPs and VOCs.

  • Temperature and material impact: The magnitude of emissions is directly tied to the nozzle temperature and filament type being used. 
  • Polylactic acid (PLA)  generally emits fewer contaminants, which makes it a safer material choice.
  • Acrylonitrile butadiene styrene (ABS) and nylon typically print at higher temperatures and consequently release significantly more UFPs and VOCs.
Teacher explaining 3D printing setup to attentive students in classroom. Various instructional materials and books are visible in background with neatly arranged equipment

3D Printing in Industrial Applications

3D printing is a critical tool for manufacturing parts for products in the electronic, aerospace defense, and automotive sectors. This industrial adoption requires adherence to safety standards and engineering controls to manage the high UFP and VOC emissions in a commercial-scale environment.

Emission characterization in battery fabrication

Advancements in additive manufacturing have extended into the energy sector, particularly in lithium-ion battery fabrication. In collaboration with the University of Houston and UL Research Institutes’ Electrochemical Safety — another unit under UL Resarch Institutes — our research focuses on emission assessments during slurry processing and printing of battery materials.

  • Battery manufacturing: This study investigates the generation and characteristics of emissions during the fabrication and printing of lithium-ion battery components, particularly during slurry preparation and layer deposition.
  • Safety relevance: Battery fabrication requires consistent emission profiling. Characterizing emissions is essential for understanding potential exposure hazards and devising appropriate mitigation strategies. 
  • Collaborative framework: This project builds upon the ongoing research conducted by the University of Houston and UL Research Institutes’ Electrochemical Safety regarding the 3D printing of solid-state batteries. The inclusion of Chemical Insights expertise further enhances the partnership through systematic testing of emissions from battery fabrication processes.
3d printing in industrial environments

How to Reduce Potential Health Hazards from Fused Filament 3D Printers

Key Resources and Standards